Numéro
J. Phys. Colloques
Volume 42, Numéro C4, Octobre 1981
Proceedings of the Ninth International Conference on Amorphous and Liquid Semiconductors
Page(s) C4-455 - C4-458
DOI https://doi.org/10.1051/jphyscol:1981495
Proceedings of the Ninth International Conference on Amorphous and Liquid Semiconductors

J. Phys. Colloques 42 (1981) C4-455-C4-458

DOI: 10.1051/jphyscol:1981495

DENSITY OF STATES STUDY IN SPUTTERED a-Si : H : EFFECT OF IMPURITIES AND H RELATED DEFECTS

P. Viktorovitch1, G. Moddel2, J. Blake2, S. Oguz2, R.L. Weisfield2 and W. Paul2

1  École Centrale de Lyon, ERA CNRS Génie Électronique (no. 661), 36 Route de Dardilly, 69130 Ecully, France.
2  Division of Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, U.S.A.


Abstract
We observe two regimes in the variation of gap size (E04) and density of states (DOS) as a function of H-content (cH) in sputtered a-Si : H. In the first regime, an increase in cH from 5 to 17% is accompanied by an exponential functional decrease of the DOS near midgap, which varies also directly with E04 over a wide range of preparation conditions. In the second regime, additional incorporation of H beyond 17% fails to further decrease the DOS (with cH and E04), which shows a saturation with scatter. This behavior is interpreted in terms of H-induced and residual impurity related defects. Variation of the DOS in the lower half of the gap, responsible for hole trapping, is observed via the hole mobility-lifetime product, which exhibits a dramatic drop with impurity incorporation (P, O) and deteriorates for increasing cH in the second regime.