Issue
J. Phys. Colloques
Volume 47, Number C8, Décembre 1986
EXAFS and Near Edge Structure IV
Page(s) C8-517 - C8-520
DOI https://doi.org/10.1051/jphyscol:1986896
EXAFS and Near Edge Structure IV

J. Phys. Colloques 47 (1986) C8-517-C8-520

DOI: 10.1051/jphyscol:1986896

SURFACE Ni OXIDE STUDIED BY OXYGEN K-XANES

I. DAVOLI1, 2, M. TOMELLINI2 et M. FANFONI2

1  Dipartimento di Matematica e Fisica, Università di Camerino, I-62032 Camerino, Italy
2  PULS (Istituto Nazionale di Fisica Nucleare / CNR, Laboratori Nazionali di Frascati, I-00044 Frascati, Italy


Abstract
We have studied the surface Ni oxide by XANES techniques at the oxygen K-edge. The spectra were detected by partial yield spectroscopy, in the range of 520-570 eV at the "Grasshopper" beam line of the Frascati Syncrotron Radiation Facility. We find that the oxygen react with nickel producing an oxide where the local structure at room temperature is similar to the defective (Ni(1-δ)O). Data are interpreted following the recent electronic-configuration interaction theory.