Numéro
J. Phys. Colloques
Volume 42, Numéro C6, Décembre 1981
International Conference on Phonon Physics
Page(s) C6-326 - C6-328
DOI https://doi.org/10.1051/jphyscol:1981695
International Conference on Phonon Physics

J. Phys. Colloques 42 (1981) C6-326-C6-328

DOI: 10.1051/jphyscol:1981695

THERMAL EXPANSION OF ALKALI-GRAPHITE INTERCALATION COMPOUNDS

S.E. Hardcastle et H. Zabel

Loomis Laboratory of Physics and Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, ILL. 61801, U.S.A.


Abstract
The c-axis thermal expansion of several alkali-graphite intercalation compounds has been measured by means of x-ray scattering between 15 and 300 K. The thermal expansion depends strongly on the stage of the compound and is largest for C8M (M=K, Rb, Cs) compounds. The data have been analyzed in terms of an one-dimensional quasi-harmonic approximation, which yields Grüneisen parameters two or three times as large as for pristine graphite.