Numéro
J. Phys. Colloques
Volume 42, Numéro C6, Décembre 1981
International Conference on Phonon Physics
Page(s) C6-637 - C6-639
DOI https://doi.org/10.1051/jphyscol:19816185
International Conference on Phonon Physics

J. Phys. Colloques 42 (1981) C6-637-C6-639

DOI: 10.1051/jphyscol:19816185

NEUTRON, X-RAY AND LATTICE DYNAMICAL STUDIES OF Sb2 S3

K.R. Rao1, 2, V. M. Padmanabhan1, Neutron Physics Division, P.R. Vijayaraghavan1, 2 et S.L. Chaplot1, 2

1  Bhabha Atomic Research Centre, Trombay, Bombay 400 085, India
2  Nuclear Physics Division


Abstract
'Elastic'neutron and x-ray diffraction patterns from crystals of Sb2S3 (minera1 stibnite) show that the crystals, while ordered along <010> (the chain axis) , are disordered about <010>. Extensive diffuse intensity perpendicular to <010> direction is observed. Inelastic scattering studies using 1.4Å neutrons did not lead to any soft TA modes with q in the (OkO) plane and polarised along <010>. A few longitudinal phonons along <010> are seen. Results from lattice dynamical calculations based on a rigid ion model (with covalent bonding included) are discussed in the context of these observations.