| Numéro |
J. Phys. Colloques
Volume 48, Numéro C9, Décembre 1987
X-Ray and Inner-Shell ProcessesVol. 1 |
|
|---|---|---|
| Page(s) | C9-981 - C9-988 | |
| DOI | https://doi.org/10.1051/jphyscol:19879175 | |
X-Ray and Inner-Shell Processes
Vol. 1
J. Phys. Colloques 48 (1987) C9-981-C9-988
DOI: 10.1051/jphyscol:19879175
Sektion Chemie der Karl-Marx-Universität Leipzig, Talstrasse 35, DDR-7010 Leipzig, G.D.R.
Vol. 1
J. Phys. Colloques 48 (1987) C9-981-C9-988
DOI: 10.1051/jphyscol:19879175
STRUCTURE INVESTIGATION OF METAL COMPLEXES BY MEANS OF X-RAY EMISSION AND PHOTOELECTRON SPECTROSCOPY
A. MEISEL, R. SZARGAN, K.-H. HALLMEIER, I. UHLIG and J.-A. MOMANDSektion Chemie der Karl-Marx-Universität Leipzig, Talstrasse 35, DDR-7010 Leipzig, G.D.R.
Abstract
The ability of the Ni Lα, β, S Kβ, O Kα, and Ni 2p spectra to distinguish between chemical states of atoms and their various environments is applied for structural characterization of nickel coordination compounds. In addition to the well documented influences of metal oxidation state and the electronegativity, the dependence of the energy shifts and intensity ratios upon the coordination geometry and the chelate ligand structure is discussed.