| Numéro |
J. Phys. Colloques
Volume 48, Numéro C7, Décembre 1987
1st International Laser M2P Conference
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|---|---|---|
| Page(s) | C7-343 - C7-346 | |
| DOI | https://doi.org/10.1051/jphyscol:1987782 | |
1st International Laser M2P Conference
J. Phys. Colloques 48 (1987) C7-343-C7-346
DOI: 10.1051/jphyscol:1987782
Department of chemistry, Kansas State Univertity, Manhattan, KS 66506, U.S.A.
J. Phys. Colloques 48 (1987) C7-343-C7-346
DOI: 10.1051/jphyscol:1987782
GENERATION AND QUENCHING OF NF(a) AND NF(b) MOLECULES
D.W. SETSER, H. CHA, E. QUIÑONES and K. DUDepartment of chemistry, Kansas State Univertity, Manhattan, KS 66506, U.S.A.
Abstract
The Ar(3P0, 2) + NF2 and 2F + HN3 reactions have been developed as sources of NF(b1Σ+) and NF(a1Ɗ) molecules, respectively, in a flow reactor. The decay kinetics for these molecules in the presence of added reagent can be studied using standard flow reactor techniques. Room temperature quenching rate constants for both molecules are reported for several reagents and compared to results for the isoelectronic O2(a) and O2(b) molecules.