Issue
J. Phys. Colloques
Volume 47, Number C2, Mars 1986
32 nd International Field Emission Symposium / 32ème Symposium International d'Emission de Champ
Page(s) C2-381 - C2-387
DOI https://doi.org/10.1051/jphyscol:1986259
32 nd International Field Emission Symposium / 32ème Symposium International d'Emission de Champ

J. Phys. Colloques 47 (1986) C2-381-C2-387

DOI: 10.1051/jphyscol:1986259

ATOM-PROBE STUDY OF SURFACE SEGREGATION OF Ni-Cu ALLOYS

T. HASHIZUME1, T. SAKURAI1 et H.W. PICKERING2

1  The Institute for Solid State Physics, The University of Tokyo, Minato-ku, Tokyo, Japan
2  The Department of Materials Science and Engineering, The Pennsylvania State University, The University park, Pa 16802, U. S.A.


Abstract
A focusing-type ToF atom-probe has been designed and constructed successfully, with superb features, such as 100 % detection efficiency and precise alignment of a probing area. Using this instrument, surface segregation of the Ni-Cu alloy system was investigated in detail. Experimental evidence are presented for solute Ni segregation to the surface, contrary to the general belief that Cu atoms always segregate to the surface. A new insight is needed in surface segregation to account for this observation of Ni segregation in Ni1-xCux alloys where x is 0.84 to 1.