Numéro
J. Phys. Colloques
Volume 49, Numéro C8, Décembre 1988
Proceedings of the International Conference on Magnetism
Page(s) C8-1513 - C8-1514
DOI https://doi.org/10.1051/jphyscol:19888697
Proceedings of the International Conference on Magnetism

J. Phys. Colloques 49 (1988) C8-1513-C8-1514

DOI: 10.1051/jphyscol:19888697

DIRECT OBSERVATION OF EXCHANGE SPLITTINGS IN RARE EARTH DIMERS BY INELASTIC NEUTRON SCATTERING

A. Dönni1, A. Furrer1, H. Blank2, A. Heidemann2 et H. U. Güdel3

1  Laboratorium für Neutronenstreuung ETHZ, 5303 Würenlingern, Switzerland
2  ILL, 38042 Grenoble, France
3  Institut für anorganische Chemie, Freiestrasse 3, 3000 Bern 9/Switzerland


Abstract
The crystal structures of the insulating dimer compounds Cs3R2Br9 (R = Tb3+, Dy3+, Ho3+, Er3+, Yb3+) were determined by neutron diffraction at 8 K and 295 K. Magnetic dimer excitations were measured by inelastic neutron scattering. Exchange splittings were thus directly determined. In the Tb3+, Dy3+ and Yb3+ dimers the interaction is of the Heisenberg type.