Numéro
J. Phys. Colloques
Volume 49, Numéro C8, Décembre 1988
Proceedings of the International Conference on Magnetism
Page(s) C8-863 - C8-864
DOI https://doi.org/10.1051/jphyscol:19888390
Proceedings of the International Conference on Magnetism

J. Phys. Colloques 49 (1988) C8-863-C8-864

DOI: 10.1051/jphyscol:19888390

STUDY OF THE MAGNETIC INTERACTIONS IN A BIMETALLIC COMPLEX CuII (salen) NiII (hfa)2 BY POLARISED NEUTRON DIFFRACTION

B. Gillon1, Y. Journaux2 et O. Kahn2

1  Laboratoire Léon Brillouin (CEA-CNRS), CEN Saclay, 91191 Gif-sur-Yvette Cedex, France
2  Laboratoire de Spectrochimie des Eléments de Transition, UA420, Université Paris-Sud, 91405 Orsay Cedex, France


Abstract
The long distance magnetic interactions in the complex CuII (salen) NiII (hfa)2 are investigated by polarised neutron diffraction, which permits to determine the magnetisation density. The role of the oxygen bridging ligands in the antiferromagnetic Cu... Ni interaction is demonstrated.