Numéro
J. Phys. Colloques
Volume 42, Numéro C6, Décembre 1981
International Conference on Phonon Physics
Page(s) C6-743 - C6-745
DOI https://doi.org/10.1051/jphyscol:19816218
International Conference on Phonon Physics

J. Phys. Colloques 42 (1981) C6-743-C6-745

DOI: 10.1051/jphyscol:19816218

PRESSURE DEPENDENCE OF IMPURITY INDUCED RAMAN SCATTERING SPECTRA I N ZnS CRYSTALS

M. Zigone1, M. Vandevyver2 et D.N. Talwar2

1  Laboratoire de Physique des Solides, associé au C.N.R.S., Université Pierre et Marie Curie, 4, Place Jussieu, 75230 Paris Cedex 05, France
2  C.E.A., C.E.N.S., Boîte Postale n° 2, 91190 Gif-sur-Yvette, France


Abstract
Raman scattering from zinc sulphide crystals containing a transition metal substitutional impurity (Mn and Co) is reported at different pressures up to 40 kbar. Numerical calculations of these impurity induced Raman intensities are also made on the basis of Green's function theory. It is shown that the features observed in the Raman spectra of the above crystals may be interpreted as a series of resonant modes due to the weakening of the impurity-sulfur bonds by about 20 %.