| Numéro |
J. Phys. Colloques
Volume 41, Numéro C8, Août 1980
Fourth International Conference on Liquid and Amorphous Metals
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|---|---|---|
| Page(s) | C8-20 - C8-23 | |
| DOI | https://doi.org/10.1051/jphyscol:1980805 | |
Fourth International Conference on Liquid and Amorphous Metals
J. Phys. Colloques 41 (1980) C8-20-C8-23
DOI: 10.1051/jphyscol:1980805
1 Physics Department, University of Warwick, Coventry CV4 7AL, England.
2 Physics Department, Oregon State University, Corvallis, Oregon, U.S.A.
J. Phys. Colloques 41 (1980) C8-20-C8-23
DOI: 10.1051/jphyscol:1980805
209Bi NMR IN MOLTEN Bi-BiBr3 MIXTURES
R. Dupree1 et J.A. Gardner21 Physics Department, University of Warwick, Coventry CV4 7AL, England.
2 Physics Department, Oregon State University, Corvallis, Oregon, U.S.A.
Abstract
The 209Bi shift and relaxation have been measured in several Bi-BiBr3 mixtures. The behaviour is very different from that observed in Bi-BiI3 mixtures. The 209Bi shift decreases strongly as BiBr3 is added to Bi and the relaxation rate increases rapidly. The NMR data give strong evidence for the formation of short-lived BiBr3 "molecules" in the metal rich mixtures.