| Numéro |
J. Phys. Colloques
Volume 41, Numéro C6, Juillet 1980
THIRD EUROPHYSICS TOPICAL CONFERENCELATTICE DEFECTS IN IONIC CRYSTALS |
|
|---|---|---|
| Page(s) | C6-434 - C6-435 | |
| DOI | https://doi.org/10.1051/jphyscol:19806111 | |
THIRD EUROPHYSICS TOPICAL CONFERENCE
LATTICE DEFECTS IN IONIC CRYSTALS
J. Phys. Colloques 41 (1980) C6-434-C6-435
DOI: 10.1051/jphyscol:19806111
Department of Chemistry, University of Wisconsin, Madison, WI 53706, U.S.A.
LATTICE DEFECTS IN IONIC CRYSTALS
J. Phys. Colloques 41 (1980) C6-434-C6-435
DOI: 10.1051/jphyscol:19806111
Laser spectroscopy of defect equilibria in fluorite materials
J. C. WrightDepartment of Chemistry, University of Wisconsin, Madison, WI 53706, U.S.A.
Résumé
Une technique pour exciter sélectivement des sites précis dans les cristaux alcalinoterreux dopés aux terres rares sera décrite. La technique a permis la caractérisation des états d'équilibre des imperfections. Les variations, avec la concentration et la température, de la distribution des sites seront décrites.
Abstract
A new method using laser spectroscopy has been developed and applied to the study of defects in alkaline earth fluoride crystals. The concentrations of all the defects have been determined as a function of concentration and temperature. The measurements show that the simple defect equilibria previously assumed for fluorites is incorrect and a new model is proposed.