Numéro
J. Phys. Colloques
Volume 41, Numéro C6, Juillet 1980
THIRD EUROPHYSICS TOPICAL CONFERENCE
LATTICE DEFECTS IN IONIC CRYSTALS
Page(s) C6-520 - C6-521
DOI https://doi.org/10.1051/jphyscol:19806136
THIRD EUROPHYSICS TOPICAL CONFERENCE
LATTICE DEFECTS IN IONIC CRYSTALS

J. Phys. Colloques 41 (1980) C6-520-C6-521

DOI: 10.1051/jphyscol:19806136

On the luminescence of RbI : Pb2+ at liquid helium temperature

S. B. S. Sastry et S. Sapru

Department of Physics, Indian Institute of Technology, Madras-600 036, India


Abstract
Results on polarized luminescence measurements made on RbI : Pb2+ at 4.7 K and optical absorption between LHeT and LNT are reported. From the luminescence data it is found that charge compensating vacancy (ccv) occupies near neighbour (28 %) and next near neighbour (72 %) sides indicating that as temperature goes down the ccv moves nearer to the impurity ion. This fact is also reflected in the optical absorption spectra of the crystal taken at these temperatures. The symmetric C-band has become asymmetric indicating that near octahedral symmetry of the impurity site has changed to lower symmetries.