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Cited article:

Preparation of anatase, brookite and rutile at low temperature by non-hydrolytic sol–gel methods

Pascal Arnal, Robert J. P. Corriu, Dominique Leclercq, P. Hubert Mutin and André Vioux
J. Mater. Chem. 6 (12) 1925 (1996)
https://doi.org/10.1039/JM9960601925