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Multilayer Amorphisation by Solid-State-Reaction and Mechanical Alloying
J. Phys. Colloques 51 (1990) C4-111-C4-117
DOI: 10.1051/jphyscol:1990413
PREDICTION OF GLASS FORMATION BY SOLID STATE REACTION IN ALLOYS
L. J. GALLEGO1, J. A. SOMOZA1, H. M. FERNANDEZ1 et J. A. ALONSO21 Departamento de Física de la Materia Condensada, Facultad de Física, Universidad de Santiago, Santiago de Compostela, Spain
2 Departamento de Física Theórica, facultad de Ciencias, Universidad de Valladolid, Valladolid, Spain
Résumé
On examine les aspects thermodynamiques de l'amorphisation des alliages par réaction en état solide ; pour ce faire on utilise une démarche qui conjugue la théorie classique de l'élasticité avec le modèle de Miedema pour la chaleur de formation des alliages. La prédiction de l'intervalle de concentrations dans lequel on peut trouver des phases amorphes demande de construire les diagrammes d'énergie libre correspondants, qui, dans ce travail, sont présentés pour plusieurs alliages intéressants, qui montrent des comportements très différents.
Abstract
The thermodynamic aspects of the amorphization of alloys by solid state reaction are examined using a combination of classical elasticity theory and Miedema's model for the heat of formation of alloys. Prediction of the concentration range where amorphous phases can be found requires construction of the pertinent free energy diagrams. These are presented here for several alloy of interest with quite different behaviours.
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